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Chiral Lipophilic Ligands. 1. Enantioselective Cleavage of .alpha.-Amino Acid Esters in Metallomicellar Aggregates

✍ Scribed by Scrimin, Paolo; Tecilla, Paolo; Tonellato, Umberto

Book ID: 126973758
Publisher: American Chemical Society
Year: 1994
Tongue: English
Weight: 1000 KB
Volume: 59
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00094a034

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A series of lipophilic liyands, 1-3. featuring an 1,2-ethylendiamino moiety as chelating subunit, one (1, 3) or two (2) chin1 carbons, and an hydroxy function (except for 3) in the proximity of the coordination center, have been synthesized. Their Cu(I1) complexes have been investigated as catalysts