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Chiral intermediates in thiamin catalysis. Stereochemical course of the decarboxylation step in the conversion of pyruvate to acetaldehyde

✍ Scribed by Kluger, Ronald; Karimian, Khashayar; Kitamura, Kelly


Book ID
126976007
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
573 KB
Volume
109
Category
Article
ISSN
0002-7863

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Diastereoselective Addition of Chiral (2
✍ Bernhard WΓΌnsch; Sven Nerdinger πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 354 KB πŸ‘ 2 views

A novel asymmetric synthesis of 1-aryl-1,2,3,4-tetrahy-sodium in liquid ammonia and ammonium cerium(IV) nitrate, respectively, to yield the primary amines 35 and 36. The acid-droisoquinolines has been developed. The key step in this synthesis is the diastereoselective addition of homochiral (2-catal