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Chiral induction in photochemical reactions: V. Regio- and diastereoselectivity in the photochemical [ 2+2] cycloaddition of chiral cyclenone-3-carboxylates with 1,1'-diethoxyethene

✍ Scribed by Heinz Herzog; Hartmut Koch; Hans-Dieter Scharf; Aad Jan Runsink


Book ID
108371722
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
940 KB
Volume
42
Category
Article
ISSN
0040-4020

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## Abstract The copolymerizations of (__S__)‐1,2‐propanediyl and (2__S__,3__S__)‐2,3‐butanediyl bis(4‐vinyl‐benzoate)s (2a and 2b) (M~1~) with styrene (M~2~) were carried out using 2,2′‐azoisobutyronitrile in toluene at 60 Β°C. For the cyclocopolymer 3, the extent of cyclization of 3b is higher than