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Chiral induction from ligands to metal centres. A copper(II)–nitroxide complex

✍ Scribed by Christophe Lescop; Dominique Luneau; Paul Rey; Victor Ovcharenko; Galina Romanenko; Yuri Shvedenkov

Book ID
104429832
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
148 KB
Volume
4
Category
Article
ISSN
1387-1609

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Effect of Ligand Spacer on Metallosupram
Effect of Ligand Spacer on Metallosupramolecular Architectures: From a Dinuclear Copper(II) Double Helicate to a Tetranuclear Copper(II) Complex
✍ Partha Halder; Priya Ranjan Banerjee; Ennio Zangrando; Tapan Kanti Paine 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 324 KB

## Abstract Two new bis(N,O‐bidentate) Schiff base ligands with asymmetric spacers between the donor sites have been synthesized. The asymmetric ligand H~2~L^1^ self‐assembles with copper(II) ions to give rise to a dinuclear copper(II) complex [Cu~2~L^1^~2~] (1), while a more flexible ligand H~2~L^