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Chiral host-guest recognition in an ion-molecule reaction

✍ Scribed by Chu, In Hou; Dearden, David V.; Bradshaw, Jerald S.; Huszthy, Peter; Izatt, Reed M.

Book ID
126959353
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
338 KB
Volume
115
Category
Article
ISSN
0002-7863

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## Using fast atom bombardment (FAB) mass spectrometry (MS), cross-chiral relationships were confirmed for the first time for the diasteromeric host-guest complexations between the chiral crown ether host (1) and the chiral organic ammonium ion guest (2) on the basis of the relative peak intensities

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## Abstract The enantiomers of a chiral solvent can be enclathrated to a different extent in a crystal lattice consisting of tri‐__o__‐thymotide (**1**) molecules of a given handedness. This property affords a mean of studying the stereoselective interaction of a chiral environment with an enclosed