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Chiral handle-induced diastereoselectivity in an organic photorearrangement: Solution versus solid state results

✍ Scribed by Jianxin Chen; Miguel Garcia-Garibay; John R. Scheffer


Book ID
104244436
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
279 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The degree of asymmetric induction in the di-x-methane photorearrangement due to the presence of a remote chiral handle was found to vary with the nature and location of the chiral handle and with the medium in which the reaction was carried out.