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Chiral Fluoro Ketones for Catalytic Asymmetric Epoxidation of Alkenes with Oxone

โœ Scribed by Denmark, Scott E.; Matsuhashi, Hayao


Book ID
126205276
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
127 KB
Volume
67
Category
Article
ISSN
0022-3263

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Chiral ketone-catalyzed asymmetric epoxi
โœ Koichiro Matsumoto; Kiyoshi Tomioka ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 64 KB

Chiral ketones 1 and 2 bearing 1-aza-7-oxabicyclo[3.5.0]decane skeleton and their C 2 -symmetric analogue 3 were readily prepared and evaluated as a chiral dioxirane precursor for asymmetric epoxidation of olefins with Oxone ยฎ . The ketone 2, bearing a diphenyl steric wall, was not effective and gav