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Chiral enamide. Part 1: Epoxidations of chiral enamides. A viable approach to chiral nitrogen stabilized oxyallyl cations in [4+3] cycloadditions

✍ Scribed by Hui Xiong; Richard P. Hsung; Lichun Shen; Juliet M. Hahn

Book ID: 104251267
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 191 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)00849-3

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✦ Synopsis

The first study of stereoselective epoxidations of chiral enamides is described here. Its potential in the synthesis of chiral a-keto aminals as a viable approach to nitrogen stabilized oxyallyl cations in stereoselective [4+3] cycloadditions is also illustrated.

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