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Chiral discrimination in fluorescence quenching

โœ Scribed by Yorozu, Takehiko; Hayashi, Koichiro; Irie, Masahiro


Book ID
127071129
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
628 KB
Volume
103
Category
Article
ISSN
0002-7863

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A study of the quenching of fluorescence of (+)-and (-) camphor in hexane by a series of chiral primary, secondary, and tertiary amines shows only very small differences in quenching rate constants for the two enantiomers. The collision complex which precedes quenching (probably charge transfer) is