The deprotonation N-Boc-pyrrolidine by i-PrLi-(S,S)-1,2-bis(N,N-dimethylamino)cyclohexane has been studied at the HF/3-21G and B3P86/6-31G\* theoretical levels. The two lowest energy complexes of the N-Boc-pyrrolidine-i-PrLi-diamine ligand, as well as the transition states leading to proton transfer
β¦ LIBER β¦
Chiral Diamines 4: A Computational Study of the Enantioselective Deprotonation of Boc-pyrrolidine with an Alkyllithium in the Presence of a Chiral Diamine
β Scribed by Wiberg, Kenneth B.; Bailey, William F.
- Book ID
- 118144624
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 261 KB
- Volume
- 123
- Category
- Article
- ISSN
- 0002-7863
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