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Chiral carboxylic acid ligands derived from camphoric acid

โœ Scribed by Mark G. Moloney; Diana R. Paul; Russell M. Thompson; Emma Wright


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
762 KB
Volume
7
Category
Article
ISSN
0957-4166

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Binuclear and polynuclear rhodium comple
โœ Z. Freixa; E. Martin; S. Gladiali; J. C. Bayรณn ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 127 KB

Two precursors of the chiral dithiolato ligands, di-[(2R)-acetylmercaptopropyl] phthalate and isophthalate, 1 and 2 respectively, were synthesized from (S)-lactic acid. Reactions of 1 and 2 with [Rh 2 (m)-OMe) 2 (cod) 2 ] (cod = 1,5-cyclo-octtadiene) yielded rhodium thiolato complexes of different n