1998 stereochemistry stereochemistry (general, optical resolution) O 0030 50 -037 Chiral C 2 -Symmetric 2,5-Disubstituted Pyrrolidine Derivatives as Catalytic Chiral Ligands in the Reactions of Diethylzinc with Aryl Aldehydes. -The scope of the title compounds as chiral catalysts in the asymmetric
Chiral C2-symmetric 2,5-disubstituted pyrrolidine derivatives as chiral catalyst ligands in the reaction of diethylzinc with arylaldehydes
β Scribed by Min Shi; Yukihiro Satoh; Takechi Makihara; Yukio Masaki
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 196 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0957-4166
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Several new chiral auxiliaries with differing steric and electronic environments, such as β£,β£Π-dimethyl-2,6-pyridinedimethanol, β£,β£Π-ditrifluoromethyl-2,6pyridinedimethanol, β£,β£Π-dipentafluoroethyl-2,6-pyridinedimethanol, and β£,β£Π-diallyl-2,6pyridinedimethanol, have been examined and compared with β£