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Chiral Bis(oxazoline)copper(II) Complexes as Lewis Acid Catalysts for the Enantioselective Diels−Alder Reaction

✍ Scribed by Evans, David A.; Miller, Scott J.; Lectka, Thomas; von Matt, Peter


Book ID
120289993
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
490 KB
Volume
121
Category
Article
ISSN
0002-7863

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✍ Bai-Yuan Yang; Xiao-Min Chen; Guo-Jun Deng; Yi-Li Zhang; Qing-Hua Fan 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 158 KB

A series of copper(II) complexes, with chiral bis(oxazoline) ligands disubstituted at the carbon atom linking the two oxazolines by Fre ´chet-type polyether dendrimers, have been designed and synthesized. These complexes were used as Lewis acid catalysts in enantioselective aldol reactions in aqueou