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Chiral Bis(N-arylamino)phosphine-oxazolines: Synthesis and Application in Asymmetric Catalysis

✍ Scribed by Marc Schönleber; Robert Hilgraf; Andreas Pfaltz

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
218 KB
Volume
350
Category
Article
ISSN
1615-4150

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Geminal Bis(sulfoximine)s: Synthesis and
Geminal Bis(sulfoximine)s: Synthesis and Applications in Asymmetric Catalysis
✍ M. Reggelin; H. Weinberger; V. Spohr 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 418 KB

## Abstract A number of __C__~2~‐symmetrical geminal bis(sulfoximine)s have been prepared for the first time and used as ligands in boron‐mediated reductions of acetophenone and copper complex‐catalyzed 1,4‐additions of diethylzinc to 2‐cyclohexenone. The copper complex of bis(sulfoximine) 46 was f