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Chiral binaphthylbisbipyridine-based copper(i) coordination polymer gels as supramolecular catalysts

✍ Scribed by He, Yabing; Bian, Zheng; Kang, Chuanqing; Cheng, Yanqin; Gao, Lianxun


Book ID
115452044
Publisher
Royal Society of Chemistry
Year
2010
Tongue
English
Weight
1019 KB
Volume
46
Category
Article
ISSN
1359-7345

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The coordination polymers 2 [(CuCN) 2 (l-2 Mepyz)], 3 [CuCN(l-2 Mepyz)] and 3 [CuCN(l-4 Mepym)] (1Β±3) (2 Mepyz = 2-methylpyrazine; 4 Mepym = 4-methylpyrimidine) may be prepared by self-assembly in acetonitrile solution at 100 Β°C (1, 3) or without solvent at 20 Β°C (2). All three contain 1 [CuCN] cha