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Chiral Benzylic Carbocations: Low-Temperature NMR Studies and Theoretical Calculations

โœ Scribed by Stadler, Daniel; Goeppert, Alain; Rasul, Golam; Olah, George A.; Prakash, G. K. Surya; Bach, Thorsten


Book ID
126035627
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
202 KB
Volume
74
Category
Article
ISSN
0022-3263

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โœ Paulo R. de Oliveira; Roberto Rittner ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 202 KB

The integration of 1 H and 13 C NMR spectra, at -90 โ€ข C in CS 2 /CD 2 Cl 2 (9 : 1), for the trans-3-chlorocyclohexanol (1), trans-3bromocyclohexanol (2), and trans-3-methoxycyclohexanol (4) showed that the equatorial-axial (ea) conformer occurs as ca 63, 63, and 69% in the conformational equilibrium