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Chiral and achiral bis(2-oxazolinylphenolato)nickel(II) complexes—synthesis, crystal structure, and catalytic properties

✍ Scribed by Wei Zhao; Yan-Long Qian; Ji-Ling Huang

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 467 KB
Volume: 22
Category: Article
ISSN: 0256-7660
DOI: 10.1002/cjoc.20040220723

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~