The 1,3-dipolar cycloaddition between N-acryloyl-oxazolidinone and diphenyl nitrone is catalyzed by chiral catalysts derived from bis(oxazoline) (R)-7 and Mg(II) perchlorate or triflate. In addition to complete regioselectivity, the endo cycloadduct can be obtained with up to 86% ee. The stereochemi
Chiral amplification in Diels-Alder and 1,3-dipolar cycloadditions catalyzed by bis(oxazoline)-Zn(II)-based chiral complexes
✍ Scribed by Stefano Crosignani; Giovanni Desimoni; Giuseppe Faita; Salvatore Filippone; Annalisa Mortoni; PierPaolo Righetti; Michele Zema
- Book ID
- 104262207
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 245 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Asymmetric hetero-Diels-Alder reactions of glyoxylate esters and Danishefsky's diene catalyzed by various chiral bis(oxazoline)-lanthanide complexes afforded the corresponding aldol adducts, which upon treatment with trifluoroacetic acid, furnished the hetero-Diels-Alder product in up to 77% enantio
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v