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Chemoselective trimethylsilylation of alcohols catalyzed by saccharin sulfonic acid

✍ Scribed by Farhad Shirini; Mohammad Ali Zolfigol; Masoumeh Abedini

Book ID
106214066
Publisher
Springer Vienna
Year
2008
Tongue
English
Weight
358 KB
Volume
140
Category
Article
ISSN
0026-9247

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## Abstract In this paper, rapid and highly efficient trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) in the presence of catalytic amounts of high‐valent [Sn^IV^(TPP)(OTf)~2~] is reported. This catalytic system catalyzes trimethylsilylation of primary, secondary and ter