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Chemoselective reductions with sodium borohydride

✍ Scribed by Ward, Dale E.; Rhee, Chung K.


Book ID
120158828
Publisher
NRC Research Press
Year
1989
Tongue
French
Weight
420 KB
Volume
67
Category
Article
ISSN
0008-4042

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πŸ“œ SIMILAR VOLUMES


Regio- and chemoselective conjugate 1,4-
✍ Ch. Srinivasa Rao; R.T. Chakrasali; Hiriyakkanavar Ila; Hiriyakkanavar Junjappa πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 662 KB

Theor-oxoketene dithioacetals 1. are shown to undergo conjugate 1,4-reduction in highly regio-and chemoselective manner with sodium borohydride in acetic acid to afford the corresponding B-oxodithioacetals 5 in good yields. These results have been rationalized according to HSAB principle in terms of