In most cases, the water solubility of phosphorus-containing dendrimers is mainly due to the presence of hydrophilic end groups, which bear either positive or negative charges. In the first part of this paper, several methods of synthesis and functionalization of phosphorus dendrimers are described
Chemoselective Polyalkylations of Phosphorus-Containing Dendrimers
✍ Scribed by Christophe Larré; Dr. Anne-Marie Caminade; Dr. Jean-Pierre Majoral
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 557 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0044-8249
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## Abstract Various methods of synthesis of phosphorus‐containing dendrimers are described. The reactivity of several of these macromolecules is then studied at several levels, mainly on the surface, and also at the level of the branches and of the core. Functionalizations confer to these macromole
Three types of tetraazamacrocycles (1,4,8,11-tetraazacy-nature of the macrocycle, the reaction induces the formation of five-membered rings (diazaphospholanes) or of six-clotetradecane, 1,4,8,12-tetraazacyclopentadecane, and 1,4,8,11-tetraazacyclotetradecane-5,7-dione) are grafted on membered rings