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Chemoselective Phosphination of Titanacyclobutene: A Convenient Method for Synthesis of Allylphosphine Derivatives

✍ Scribed by Zhou, Yiqing; Chen, Chao; Yan, Xiaoyu; Xi, Chanjuan

Book ID
125967854
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
357 KB
Volume
33
Category
Article
ISSN
0276-7333

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πŸ“œ SIMILAR VOLUMES

t-BuOK-catalyzed addition phosphines to
t-BuOK-catalyzed addition phosphines to functionalized alkenes: a convenient synthesis of polyfunctional phosphine derivatives
✍ Tanasri Bunlaksananusorn; Paul Knochel πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 100 KB

The use of t-BuOK in DMSO allows a smooth addition of Ph 2 PH, Cy 2 PH and Ph 2 P(O)H to various functionalized alkenes leading to polyfunctional phosphines in good yields. This method has been used to prepare precursors for P,P-and P,N-ligands.