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Chemoselective oxidation with molybdenum catalyst-t-butyl hydroperoxide

✍ Scribed by Yoshiro Masuyama; Masato Takahashi; Yasuhiko Kurusu


Book ID
104233820
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
274 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Benzyltrimethylammonium tetrabromooxomolybdate is an excellent chemoselective catalyst to oxidize secondary alcohols to ketones, primary alcohols to esters, and aldehydes to acids or esters with t-butyl hydroperoxide.


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Aluminosilicate-catalyzed oxidation of a
✍ Laura Palombi; Francesco Bonadies; Arrigo Scettri πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 223 KB

## Ε½ . The catalytic abilities of commercial K10-montmorillonite and molecular sieves 4 A and 13 X vs. oxidation of alcohols by t-butyl hydroperoxide were investigated. The K10-montmorillonite-catalyzed oxidation of secondary benzylic alcohols was found to proceed in good yield and selectivity wit