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Chemoselective oxidation of sulfides to sulfones with potassium hydrogen persulfate

โœ Scribed by Barry M. Trost; Dennis P. Curran

Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
186 KB
Volume
22
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Potassium hydrogen persulfate in aqueous methanol was found to be a convenient, inexpensive, and chemoselective reagent for the oxidation of sulfides to sulfones and sulfoxides in the presence of other common functional groups.

๐Ÿ“œ SIMILAR VOLUMES

Diastereoselective oxidation of sulfides
Diastereoselective oxidation of sulfides to sulfoxides with potassium peroxymonosulfate
โœ George J. Quallich; J. William Lackey ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 153 KB

Potassium peroxymonosulfate oxidation of suffides to suffoxides occurs with high diastereosebctivky. In seeking a preparative process for the skfe chain of antibacterial CP-70,429, penem 1. we prepared the sulfoxkle side chain a as a 4:l mixture of ~6~6 and & sulfoxides by oxkfatbn of the sulfide 2