Chemoselective noncatalytic addition of secondary phosphine chalcogenides to citral
β Scribed by N. K. Gusarova; N. I. Ivanova; N. A. Konovalova; A. I. Albanov; L. M. Sinegovskaya; N. D. Avseenko; B. G. Sukhov; A. I. Mikhaleva; A. V. Gusarov; B. A. Trofimov
- Book ID
- 111459191
- Publisher
- Springer
- Year
- 2007
- Tongue
- English
- Weight
- 139 KB
- Volume
- 77
- Category
- Article
- ISSN
- 1070-3632
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Secondary phosphines 1-3 react readily with N-vinylpyrroles 4 and 5 under radical initiation to give regiospecifically anti-Markovnikov adducts, diorganyl-2-(1-pyrrolyl)ethylphosphines 6a-d, highly reactive building blocks for organic synthesis, in 88-91% yields.