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Chemoselective carbonyl alkylation and reduction of aldehydes or ketones

โœ Scribed by Keiji Maruoka; Yoshitaka Araki; Hisashi Yamamoto


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
269 KB
Volume
29
Category
Article
ISSN
0040-4039

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โœ Glenn C. Andrews ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Ammonia borane and primary amine boranes are highly chemoselective reducing agents for aldehydes and ketones. There has been much recent interest in the development of chemoselective1s2 reducing agents capable of distinguishing aldehyde and ketone functionality in a predictable manner. 'a-si While a

tert-Alkylation of Ketones and Aldehydes
โœ Doz. Dr. Manfred T. Reetz; Dipl.-Chem. Wilhelm F. Maier ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 213 KB ๐Ÿ‘ 2 views

attempted to prepare configurationally pure (I). Our aim was achieved by double Kolbe electrolysis starting from (2,Z)- IJ-cyclooctadiene (2) (cf. Scheme 1). 0 a ) 5 7 % , b , c ) 5 5 % \* COzR C02R COZH OZCH3