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Chemoselective aerobic oxidation of 4-allylanisol by Fe(III) porphyrins in an aqueous system

✍ Scribed by Olena Vakuliuk; Francesco G. Mutti; Miguel Lara; Daniel T. Gryko; Wolfgang Kroutil

Book ID: 104099061
Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 371 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.03.050

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✦ Synopsis

The allyl moiety of 4-allyl-anisol was oxidized in the presence of a Fe(III) porphyrin derivative to the corresponding a,b-unsaturated aldehyde in an initial oxidation step with perfect chemoselectivity. Molecular oxygen was employed as the sole environmental innocuous oxidant. The reaction was performed in an aqueous buffer/CH 2 Cl 2 mixture using the detergent Tween 80 to homogenize the system.

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