Chemorheological study of DGEBA/IPD system for reactive rotational molding (RRM)
✍ Scribed by E. Mounif; V. Bellenger; P. Mazabraud; F. Nony; A. Tcharkhtchi
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 269 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
Abstract
The identification of kinetic parameters controlling the crosslinking of Diglycidyl ether of bisphenol/isophorone diamine reactive system was achieved via optimization program (Inverse method) based on Fourier transform near infrared spectroscopy results. The reactivity ratio (k~2~/k~1~) was determined using a new method based on the variation of amine conversion ratio versus epoxy conversion ratio. Gelation and vitrification of the reactive system were also analyzed. Time, temperature, transformation diagram was established to assess the rotational molding of this reactive system. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010