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Chemometric analysis of mass spectra of cis and trans fatty acid picolinyl esters

✍ Scribed by Torben Leth

Book ID
105900891
Publisher
Springer
Year
1997
Tongue
English
Weight
222 KB
Volume
205
Category
Article
ISSN
0044-3026

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The electron impact (EI) mass spectral analysis of the picolinyl esters of nine positional isomers of conjugated diacetylenic fatty acids showed prominent M + and [M-l] + peaks. In all cases there was a regular series of ions 14 amu apart in the high molecular weight range until the triple bond syst

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Picoliiyl and methyl ester derivatives of all the isomeric thialaurates and thiastearates, together with some dithiastearates, have been characterized by gas chromatography/mass spectrometry. The picolinyl ester derivatives give simple electron impact mass spectra in which ions formed by cleavage at