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Chemo- and Regioselective Intermolecular Cyclotrimerization of Terminal Alkynes Catalyzed by Cationic Rhodium(I)/Modified BINAP Complexes: Application of One-Step Synthesis of Paracyclophanes.

✍ Scribed by Ken Tanaka; Kazuki Toyoda; Azusa Wada; Kaori Shirasaka; Masao Hirano

Publisher: John Wiley and Sons
Year: 2006
Weight: 45 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200611044

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📜 SIMILAR VOLUMES

Chemo- and Regioselective Intermolecular

Chemo- and Regioselective Intermolecular Cyclotrimerization of Terminal Alkynes Catalyzed by Cationic Rhodium(I)/Modified BINAP Complexes: Application to One-Step Synthesis of Paracyclophanes

✍ Ken Tanaka; Kazuki Toyoda; Azusa Wada; Kaori Shirasaka; Masao Hirano 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 195 KB 👁 2 views

## Abstract A highly regioselective intermolecular cyclotrimerization of terminal alkynes has been developed based on the use of the cationic rhodium(I)/DTBM‐Segphos complex. This method can be applied to a variety of terminal alkynes to provide 1,2,4‐trisubstituted benzenes in high yield and with

Highly Chemo- and Regioselective Intermo

Highly Chemo- and Regioselective Intermolecular Cyclotrimerization of Alkynes Catalyzed by Cationic Rhodium(I)/Modified BINAP Complexes.

✍ Ken Tanaka; Kaori Shirasaka 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 163 KB 👁 2 views