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Chemistry of Ylids. X. Diphenylsulfonium Alkylides--A Stereoselective Synthesi of Epoxides

✍ Scribed by Johnson, A. William.; Hruby, Victor J.; Williams, Joseph L.

Book ID
126288640
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
731 KB
Volume
86
Category
Article
ISSN
0002-7863

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The sulphur ylide-mediated synthesis of epoxides from aldehydes with in situ generation of diazocompounds has been used to prepare, for the first time, a stable epoxyferrocene, trans-2-phenyl-3-ferrocenyloxirane 3. By means of a chiral sulphide, oxirane 3 has been obtained with high enantioselectivi