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Chemistry of the Novel Oxo Half-Sandwich Complex (η5-C5Me5)ReO3: Functionalization and Aggregation

✍ Scribed by Prof. Dr. Wolfgang A. Herrmann; Dr. Ricardo Serrano; Ulrich Küsthardt; Prof. Dr. Manfred L. Ziegler; Dr. Ernst Guggolz; Thomas Zahn

Publisher
John Wiley and Sons
Year
1984
Tongue
English
Weight
348 KB
Volume
23
Category
Article
ISSN
0044-8249

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✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,