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Chemistry of the Diazeniumdiolates: Z ⇌ E Isomerism

✍ Scribed by Wang, Yan-Ni; Bohle, D. Scott; Bonifant, Challice L.; Chmurny, Gwendolyn N.; Collins, Jack R.; Davies, Keith M.; Deschamps, Jeffrey; Flippen-Anderson, Judith L.; Keefer, Larry K.; Klose, John R.; Saavedra, Joseph E.; Waterhouse, David J.; Ivanic, Joseph


Book ID
127044616
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
329 KB
Volume
127
Category
Article
ISSN
0002-7863

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E/Z -Isomerism of semicyclic amidinium s
✍ S. Hartmann; V. Brecht; A. W. Frahm 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 108 KB 👁 1 views

1H and 15N NMR chemical shifts of 12 semicyclic amidinium salts are reported. Their E/Z equilibria in solution were analyzed by 1D and 2D 1H and 15N NMR techniques. In the solid state the Z-conÐguration is observed.

E–Z isomerism of anilinomethylenemalonic
✍ C. Bünz; D. Heber; U. Holzgrabe; U. Sürig 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB

## Abstract The temperature and concentration dependence of the ^1^H NMR spectra of four anilinomethylenemalonic acid derivatives were determined in CDCl~3~ and DMSO‐__d__~6~ to assign the __E__–__Z__ isomers and to investigate the formation of intra‐ and intermolecular hydrogen bonds. Chemical shi