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Chemistry of singlet oxygen. XII. Electronic effects on rate and products of the reaction with olefins

✍ Scribed by Foote, Christopher S.; Denny, Robert W.


Book ID
121328172
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
721 KB
Volume
93
Category
Article
ISSN
0002-7863

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Quenching of Singlet Oxygen by Tertiary
✍ Enrico Baciocchi; Tiziana Del Giacco; Andrea Lapi 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 83 KB

## Abstract A kinetic and product study of the reaction of a series of __α__‐methyl‐substituted __N__‐methylpiperidines with thermally generated ^1^O~2~ in MeCN was carried out. It was found that as the number of __α__‐methyl groups (Me in __α__‐position relative to the N‐atom) increases, the rate