1-Arylallenes react with singlet oxygen via 1,Zand 1,4\_cycloaddition modes giving rise to three types of carbonyl fragments. l,l-Diphenyl-and 1-methyl-1-phenylallenes react predominantly by the 1,4-mode. Plausible mechanisms are discussed for the formation of the observed products.
โฆ LIBER โฆ
Chemistry of singlet oxygen. 47. 9,10-Dicyanoanthracene-sensitized photooxygenation of alkyl-substituted olefins
โ Scribed by Araki, Yasuhiko; Dobrowolski, Diane C.; Goyne, Thomas E.; Hanson, Douglas C.; Jiang, Zhi Qin; Lee, Kenneth J.; Foote, Christopher S.
- Book ID
- 127094886
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 782 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0002-7863
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