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Chemistry of singlet oxygen. 35. Nature of intermediates in the photooxygenation of sulfides

✍ Scribed by Gu, Chee-Liang; Foote, Christopher S.; Kacher, Mark L.


Book ID
127289326
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
305 KB
Volume
103
Category
Article
ISSN
0002-7863

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Chemistry of singlet oxygen. Dye-sensiti
✍ Ihsan Erden; Tomas R. Martinez πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 315 KB

1-Arylallenes react with singlet oxygen via 1,Zand 1,4\_cycloaddition modes giving rise to three types of carbonyl fragments. l,l-Diphenyl-and 1-methyl-1-phenylallenes react predominantly by the 1,4-mode. Plausible mechanisms are discussed for the formation of the observed products.