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Chemistry of polynuclear metal halides. IX. Crystal and molecular structure of bis(tetramethylammonium) hexachloro(dodeca-.mu.-chloro-hexaniobate), [(CH3)4N]2[(Nb6Cl12)Cl6]

✍ Scribed by Koknat, F. W.; McCarley, R. E.

Book ID: 127121967
Publisher: American Chemical Society
Year: 1972
Tongue: English
Weight: 686 KB
Volume: 11
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic50110a031

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Chemistry of polynuclear metal halides.

Chemistry of polynuclear metal halides. XI. Crystal and molecular structure of tris(tetramethylammonium)hexachloro(dodeca-.mu.-chloro-hexaniobate), [(CH3)4N]3[Nb6Cl12)Cl6]

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Facile Reduction of Early Transition Metal Halides with Nonconventional, Mild Reductants. Part 5. Gallium and Gallium Dichloride, New Solid-State Reductants in Preparative Transition Metal Chemistry. New, Lower Temperature Syntheses and Convenient Isolation of Hexatantalum Tetradecachloride Octahydrate, Ta6(μ-Cl)12Cl2 (OH2)4×4H2O, and Synthesis and Solid-State Structure of a Tetraalkylammonium Derivative, [N(CH2Ph)Bu3]4 [Ta6(μ-Cl)12Cl6], of the Reduced [Ta6(μ-Cl)12]2+ Cluster Core.

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