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Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 97. Synthesis and crystal structures of the molybdenumditungsten compounds [MoW2{�-?,?? : ?4-C(Ph)C(Ph)C(C6H4Me-4)C(C6H4Me-4)}(CO)6(?-C5H5)2]�2CH2Cl2 and [MoW2(�-C2Ph2){�-C2(C6H4Me-4)2}(CO)4(?-C5H5)2]�0.5CH2Cl2

✍ Scribed by Carriedo, Gabino A.; Howard, Judith A. K.; Jeffery, John C.; Sneller, Kathleen; Stone, F. Gordon A.; Weerasuria, A. Mala M.


Book ID
127022758
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
784 KB
Volume
3
Category
Article
ISSN
1472-7773

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## CeH5CHzCsH4)2GdCl.THF]2 (1) and ( C ~H ~C H Z C ~H ~) ~E ~C I . T H F (2) were prepared by the reaction of LnC13 ( Ln=Gd, Er) with benzylcyclopentadienyl sodium in THF and characterized by elemental analysis, IR, 'H NMR, 13C NMR, MS and thermal gravimetry. The crystal structures of both compoun