## Abstract Review: 38 refs.
Chemistry of pentacoordinated anti-apicophilic phosphorus compounds
โ Scribed by Junji Kobayashi; Takayuki Kawashima
- Book ID
- 108109801
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 607 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1631-0748
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๐ SIMILAR VOLUMES
Aminoacyl adenylate pentacoordinated phosphorus compounds were analyzed by field desorption (FD) and fast atom bombardment (FAB) mass spectrometries, together with the B/E linked scan technique, and their mass spectral fragmentation pathways were investigated. For the five bonds (one P-N bond, three
Geometry optimizations at the HF/3-21G(\*) and HF/6-31G\* levels of ab initio theory have been carried out for various isomers of model disubstituted phosphoranes PH:>XY(X, Y=OH, CH3, NH2, and SH). Reasonable agreement was obtained between the optimized geometries and available crystal structure dat