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Chemistry of nitrenium ions. IX. Discrete existence of singlet and triplet nitrenium ions

โœ Scribed by Gassman, Paul G.; Cryberg, Richard L.


Book ID
126793388
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
237 KB
Volume
91
Category
Article
ISSN
0002-7863

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Photogenerated nitrenium ions: Singlet a
โœ Rebecca J. Robbins; Daniel E. Falvey ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 419 KB

Photolysis of an antbra&um salt. 5-m~yl-3-N-re~~-~~l-2,l-benzisoxazolium tetratYwobomte (la) gives the we nitrenium ion 2a. Under dir& pbotolysis of la, in the presents of m&ophiles (i.e. ROH), quinone imii ethers such tta (6) are the major product. Triplet gensitized . uradSongivesbotb6andtheparen