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Chemistry of naphthazarin derivatives. 12. Synthesis and investigation of prototropic tautomerism of 3-(alk-1-enyl)-2-hydroxynaphthazarins

✍ Scribed by A. Ya. Yakubovskaya; N. D. Pokhilo; V. P. Glazunov; V. Ph. Anufriev; G. B. Elyakov


Book ID
106519518
Publisher
Springer
Year
2004
Tongue
English
Weight
490 KB
Volume
53
Category
Article
ISSN
1573-9171

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2-(AIk-l-enyl)-l,3,2-diazaphospholidine 2-oxides 4, containing the trans-N,N'-dihenzylcyclohexane-l,2diamine chiral auxiliary, may he prepared by palladium(0)-mediated coupling of the phosphorous acid derivative 3 with alkenyi halides. The X-ray crystal structure of the prop-l-enyl compound 4b has b