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Chemistry of Ethylenimine. VIII. Stereospecificity in the Pyrolytic Rearrangement of 1-(p-Nitrobenzoyl)-2-benzylaziridine 1

✍ Scribed by Kashelikar, D. V.; Fanta, Paul E.


Book ID
120089429
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
245 KB
Volume
82
Category
Article
ISSN
0002-7863

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## Abstract 7‐Phenylcycloheptatriene‐1,3,5 rearranges on heating to a mixture of the 3‐, 1‐ and 2‐isomers. These are formed in the order indicated by successive trans‐annular 1‐5 shifts of hydrogen. The isomerization of the 7‐ to the 3‐isomer, by which the trienic and aromatic systems enter into co