Chemistry of dioxiranes. 10. Oxidation of quadricyclane and norbornadiene by dimethyldioxirane
β Scribed by Murray, Robert W.; Pillay, M. Krishna; Jeyaraman, Ramasubba
- Book ID
- 120085060
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 741 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-3263
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A comparison of the diastereoselectivity and the chemoselectivity (epoxidation versus allylic oxidation) attained in the oxidation of cyclopentenols using dimethyldioxirane and methyl(trifluoromethyl)dioxirane is reported. The results indicate that with both dioxiranes diastereoselective epoxidation
The solvent-dependent shift in the regioselectivity of the ge-allylic alcohols, additional steric interactions control the Οfacial selectivity in the conformationally fixed transition raniol epoxidation by methyl(trifluoromethyl)dioxirane (TFD) reveals that as for the less reactive dimethyldioxirane