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Chemistry of Conjugate Anions and Enols. VII. Rates of Formation and Equilibria of Enolate Anions 1,2

✍ Scribed by Subrahmanyam, G.; Malhotra, Sudarshan K.; Ringold, Howard J.


Book ID
125953628
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
293 KB
Volume
88
Category
Article
ISSN
0002-7863

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Oxidatkn of E-and Z-vinyl lithiums with silyl peroxides 5 affords silyl enol ethers 3 in good to excellent yield with retentton of configuration. This methodobgy represents a useful new procedure for the stereoand regbselective synthesis of ketone enolates.