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Chemistry of cis-Trioxatris-σ-homobenzene. Substitutions by Bivalent Nucleophiles

✍ Scribed by Dipl.-Chem. Reinhard Schwesinger; Dr. Hans Fritz; Prof. Dr. Horst Prinzbach


Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
215 KB
Volume
12
Category
Article
ISSN
0044-8249

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Chemistry of cis-Trioxatris-σ-homobenzen
✍ Prof. Dr. Horst Prinzbach; Dipl.-Chem. Clemens Kaiser; Dr. Hans Fritz 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 234 KB 👁 1 views

trimethyl phosphite (in THF) to form benzene is fast at 20°C; nevertheless, neither the disulfide nor the monosulfide can be identified as intermediates ('H-NMR) under a variety of conditions (e.g. equimolar ratio; 20 "C). Apparently, elimination of the first sulfur atom has the highest activation e