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Chemistry of carbanions. 34. Alkylation of a 1-decalone enolate with abnormal geometry

โœ Scribed by House, Herbert O.; Phillips, William V.; VanDerveer, Don


Book ID
126864817
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
845 KB
Volume
44
Category
Article
ISSN
0022-3263

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The rate of the reaction of the lithium enolate of 1-tetralone with alkyl halides was enhanced greatly in the presence of 3 equivalents of 1,1,4,7,10,10-hexamethyltriethylenetetramine. The ratio of the monoalkylated product to the dialkylated product was found to have increased under a shorter react