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Chemistry of bent bonds. XXXVI. Photolysis of substituted derivatives of 2,3-diazabicyclo[3.1.0]hex-2-ene. Simple route to certain bicyclo[1.1.0]butanes

โœ Scribed by Gassman, Paul G.; Greenlee, William J.


Book ID
126973680
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
374 KB
Volume
95
Category
Article
ISSN
0002-7863

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The photosensitized rearrangement of ary
โœ Albert Padwa; Thomas J. Blacklock; Roman Loza ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 187 KB

The triplet sensitized irradiation of 3-allyl-diaryl-substituted cyclopropenes to m.l.O]hex-2-enes proceeds via an intramolecular [2+2]-cycloaddition followed by a subsequent rearrangement of the initially formed tricycl0[2.2.0.0~~~]hexane skeleton. Previous work from this laboratory has shown that