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Chemistry of azides. II. reaction with triphenylphosphine

โœ Scribed by J.E. Franz; C. Osuch

Publisher
Elsevier Science
Year
1963
Tongue
French
Weight
249 KB
Volume
4
Category
Article
ISSN
0040-4039

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The triphenylphosphine deoxygenation of the polyperoxides, poly(styrene peroxide), poly(methyl methacrylate peroxide), and poly( a-methylstyrene peroxide) proceed via the phosphorane intermediates, which in the presence of moisture hydrolyze to give the respective diols. At higher temperatures and u