Chemistry of Anthracene-Acetylene Oligomers. Part 5. Construction of Strained Frameworks with 1,8-Anthrylene Units and Acetylene Linkers: Synthesis and Structures of Cyclic Trimers.

Chemistry of Anthracene–Acetylene Oligom

Chemistry of Anthracene–Acetylene Oligomers: Synthesis and Enantiomeric Resolution of a Chiral 1,8-Anthrylene–Ethynylene Cyclic Tetramer

✍ Shinji Toyota; Shinya Suzuki; Michio Goichi 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 262 KB

## Abstract To construct a new type of chiral π‐conjugated system, the title anthracene–acetylene oligomer containing two octyl groups at position 10 of 1,2‐alternating anthracene groups was synthesized. Each anthracene unit was connected by Sonogashira coupling, and the tetrameric precursor was cy