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Chemistry of alkoxo complexes, part II. Synthesis and characterization of some mono(chelato)mono(alkoxo)nickel(II) complexes

โœ Scribed by B. P. Baranwal; Ram C. Mchrotra

Publisher
Springer
Year
1978
Tongue
English
Weight
341 KB
Volume
3
Category
Article
ISSN
0340-4285

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Reactions of cationic rhodium(I) carbony
Reactions of cationic rhodium(I) carbonyl compounds with nucleophiles to form alkoxo, carboalkoxy and carboxylato complexes. Part II
โœ E. Wynne Evans; Mohammed B. H. Howlader; Mark T. Atlay ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Springer ๐ŸŒ English โš– 322 KB

The rhodium(I) carbonyl compounds [-Rh(CO)L2] [BF4]. 89 (L = PPh 3 or AsPh3) react with the nucleophiles OMe-, RCOO-(R = Me, Et) under nitrogen to form [Rh(OR)(CO)L2] (1)-(2) and [Rh(OOCR)(CO)L23 (7)-(i0), respectively. Addition of [Rh(CO)2(PPh3)2]-[BF4] to OMe-under nitrogen produces [Rh(COOMe)-(CO